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A kinetic study of the chlorination of tertiary alcoholamines in alkaline media |
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| Authors: | J M Antelo F Arce J L Armesto A Garcia-Verdugo F J Penedo A Varela |
| Abstract: | The kinetics of the chlorination of various tertiary alcoholamines by hypochlorite have been studied in alkaline media. A reaction mechanism consistent with the experimental results is put forward, and a relationship is established between the rate constants and the polar parameter (Σσ*) of the substituents. |
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