Disproportionation reactions between alkyl and fluoroalkyl radicals. III. A reassessment of Δ values for CFyH(3−y) radicals (y = 1,2,3) with C2H5 radicals |
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| Authors: | G. O. Pritchard K. A. Johnson W. B. Nilsson |
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| Abstract: | New determinations of the disproportionation and combination ratios between CF2H and C2H5 radicals yield (the hydrogen acceptor radical is given first) Δ(CF2H, C2H5) = 0.068 ± 0.008, and Δ(C2H5, CF2H) = 0.37 ± 0.01. A reevaluation of the existing data on CFH2 and CF3 radicals leads to the following recommended values, Δ(CFH2, C2H5) = 0.038 ± 0.006, and Δ(CF3, C2H5) = 0.11 = ± 0.02. |
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