Formation of methyl platinum complex in the reaction of methane with chloroplatinic acid |
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| Authors: | V V Lavrushko S A Lermontov and A E Shilov |
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| Institution: | (1) Institute of Chemical Physics, Chernogolovka, USSR |
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| Abstract: | The1HNMR method and chemical analysis indicate that a complex of Pt(IV) containing a CH3–Pt fragment is formed in the reaction of H2PtCl6+H2PtCl4 with methane at 120 °C in aqueous CF3CO2H. The complex was isolated from the solution as an adduct of Ph3P.
                  ,    H2PtCl6  H2PtCl4  CF3COOH 120°C    (IV),    Pt–CH3.  Ph3P ,  .
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