Analysis of the absorption and magnetic circular dichroism spectra of the hypertensive band in (h5C5H5)Ho(h8C8H8) |
| |
| Authors: | Bryan R Hollebone Martin J Stillman |
| |
| Institution: | Department of Chemistry, Carleton University, Ottawa, Ontario, Canada K1S 5B6;Department of Chemistry, University of Western Ontario, London, Ontario, Canada N6A 5B7 |
| |
| Abstract: | The solution MCD spectrum of (h5C5H5)Ho(III)(h8C8H8) is dominated by C terms but displays distinct A term under the hypersensitive 5I8 — 5G6 transition. Intermediate field analysis suggests this transition originates from the first electronic excited state and is enhanced by τ cyclopentadienyl ligand polarization. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
