The role of solvation in redox processes |
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| Authors: | Ferran Sanz Joan Bertran |
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| Affiliation: | Department de Bioestadistica, Facultat de Medicina, Universitat Autónoma de Barcelona. Bellaterra, Barcelona Spain;Department de Quimica-Fisica, Facultat de Ciencies. Universitat Autónoma de Barcelona. Bellaterra, Barcelona Spain |
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| Abstract: | In studying the role of solvation in redox processes we consider the influence of geometrical modifications in the discharge of monosolvated anion CN?-H2O. We define as “efficient” those modifications whose energy cost is less than the lowering which is produced in the ionization potential. we conclude that in the above-mentioned species the redox process is enhanced by desolvation. We try to generalise the results for the “stable” anions and cations. |
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