Photochemistry in the electronic ground state. Isotope separation by infrared multiphoton isomerization of complex molecules |
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| Authors: | Amnon Yogev Ruth M.J. Benmair |
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| Affiliation: | Department of Isotope Research, The Weizmann Institute of Science, Rehovot, Israel |
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| Abstract: | Isotope selective isomerization of hexafluorocyclobutene to hexafluorobutadiene by multiphoton absorption of infrared laser light has been studied. All the three possible isotopomers were separated. The wavelength dependence of the reactions, saturation of absorption and the role of inert gas in retaining the selectivity are described. |
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