Non-condon effects in the X→A electronic absorption band system of sulphur dioxide期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Non-condon effects in the X→A electronic absorption band system of sulphur dioxide

Authors:	W.H. Henneker W. Siebrand M.Z. Zgierski

Affiliation:	Division of Electrical Engineering, National Research Council of Canada, Ottawa, Canada K1A 0R6;Division of Chemistry, National Research Council of Canada, Ottawa, Canada, K1A 0R6

Abstract:	The anomalously long bending-mode progressions observed in the $X$ → $A$ absorption band of SO₂ are interpreted as a non-Condon effect due to a large change in OSO angle between the coupled $A$ and $B$ states.

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