Production of electronically excited atoms. H + Br2 → HBr + Hb(*), H + HBr → H2 + Br(*) |
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| Authors: | SHP Bly D Brandt JC Polanyi |
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| Institution: | Department of Chemistry, University of Toronto, Toronto, Canada M5S IA1 |
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| Abstract: | By measurement of infrared chemiluminescence we have obtained for the branching ratio of the room temperature reaction H + Br2 (1), k*1/k1 = 0.015 ± 0.004 and for H + HBr (2), k*2/k2 ? 0.013. For H + Br2 → HBr(υ· ? 6) + Br (1), the detailed rate constant k(υ* = 6) = 0.014 ± 0.003 relative to k(υ· = 4) = 100. |
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