Surface-hopping model for near-resonant electronic energy transfer |
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Authors: | J.I. Steinfeld D.G. Sutton |
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Affiliation: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA;Aerophysics Laboratory, The Ivan A. Getting Laboratories, The Aerospace Corporation, El Segundo, California 90245, USA |
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Abstract: | A surface-hopping model is applied to near-resonant electronic energy transfer in the NFBi and O2I systems. Multiple surface crossings occur in NFBi at ca. 8 A, corresponding well with measured transfer cross section of 200 A2. A Landau-Zener model yields the temperature dependence of the thermally averaged cross section for the laser pumping reaction, O*2(a1Δ) + I(2P) → O2(X3Σ?g) + 1*(2P). |
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