Final-state intensities in photoelectron spectra of 4f electrons as predicted by relativistic calculations |
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| Authors: | N. Beatham P.A. Cox A.F. Orchard I.P. Grant |
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| Affiliation: | Inorganic Chemistry Laboratory, University of Oxford, Oxford, UK;Department of Theoretical Chemistry, University of Oxford, Oxford, UK |
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| Abstract: | Relativistic calculations have been performed for the intensities of the various photoelectron signals expected in ionisation of a partly filled 4f subshell in lanthanoid ions. The results account for discepancies found between the predictions of non-relativistic theory and the 4f photoelectron spectra of ytterbium (III)compounds. |
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