Frequency dependence of intermolecular proton spin-lattice relaxation rate and pair-diffusion constant in neat acetonitrile -d2 |
| |
| Authors: | Tadashi Tokuhiro Juanita Freer KW Woo |
| |
| Institution: | Department of Chemistry, University of Detroit, Detroit, Michigan 48221, USA |
| |
| Abstract: | Frequency dependence of intermolecular proton spin-lattice relaxation rate (1/T1)inter(ω)] in neat acetonitrile-d2 was studied. From (1/T1)inter(ω) pair-diffusion constants were determined to be 0.281 × 10?5 and 0.237 × 10?5 cm2 s?1 at 22 and ?32.6°C, respectively. These values differ greatly from the self-diffusion constants. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
