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Infrared laser enhancement of the reaction of sulfur hexafluoride with sodium vapor
Authors:Uri Agam  Mark Eyal  Frederick R Grabiner
Institution:Department of Chemistry, Tel-Aviv University, Tel Aviv, Israel
Abstract:The vibrational energy dependence of the rate of the gas phase reaction of Na with SF6 has been determined in a diffusion cloud experiment using CO2 laser excitation. The “conversion efficiency” of ca. 40% for vibrational energy suggests a preference for vibrational over the translational energy when compared with “prior” statistical expectation.
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