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Energy transfer in one-, two-, and three-dimensionally coupled salts of divalent manganese
Authors:Gary L. McPherson  Kenneth O. Devaney  Sarah C. Willard  A.H. Francis
Affiliation:Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, USA;Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, USA
Abstract:The emission spectra of several antiferromagnetic complexes of divalent manganese (CsMnBr3, Rb2MnCl4, CsMnCl3 and KMnCl3) which contain rare-earth ion impurities have been studied as a function of temperature. In all cases there appears to be a thermally activated energy migration which often results in an efficient transfer of electronic excitation from the manganese to the rare-earth impurities.
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