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Vacuum UV emission by electronically-excited N2: The radicative lifetime of the N2(a′1Σ?u state
Authors:MP Casassa  MF Golde
Institution:Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA
Abstract:A measurement of the electronic transition moment variation for the N2(a'1Σ?uX1Σ+g) band system has allowed a reassessment of the radiative lifetime of N2(a′). Relaxation to N2(a′,υ=0) is established as the major channel for quenching of N2(a1Πg, υ = 0) molecules by Ar.
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