Vacuum UV emission by electronically-excited N2: The radicative lifetime of the N2(a′1Σ?u state |
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Authors: | MP Casassa MF Golde |
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Institution: | Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA |
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Abstract: | A measurement of the electronic transition moment variation for the N2(a'1Σ?uX1Σ+g) band system has allowed a reassessment of the radiative lifetime of N2(a′). Relaxation to N2(a′,υ=0) is established as the major channel for quenching of N2(a1Πg, υ = 0) molecules by Ar. |
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