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Strong correlation effects in the ionisation of CS2
Authors:J. Schirmer  W. Domcke  L.S. Cederbaum  W. von Niessen  L. Åsbrink
Affiliation:Facultät für Physik, Universität Freiburg, D-78 Freiburg, Germany;Institut für Physikalische Chemie, Technische Universität Braunschweig, D-33 Braunschweig, Germany;Department of Physics, The Royal Institute of Technology, S-10044 Stockholm, Sweden
Abstract:The Hell photoelectron spectrum of CS2 is presented. This spectrum is investigated by two different Green's function calculations. For the outer valence region the origin and assignment of satellite lines of significant intensity is clarified. Strong final state correlation effects are found for the inner valence region showing the so-called breakdown of single-particle picture of ionisation.
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