Direct observation of free rotor states in compounds with hindred internal rotation |
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| Authors: | Nancy S True Robert K Bohn |
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| Institution: | Department of Chemistry and Institute of Materials Science, The University of Connecticut, Storrs, Connecticut 06268, USA |
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| Abstract: | Low-resolution microwave spectra of species torsionally excited above an internal rotation barrier are observed. Although the population of a single excited state is not large, the total population of these spectrally unresolved states is often sufficient to yield intense band spectra. |
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