13C NMR investigation of the structure of cationic carbonyls in transition metal zeolites |
| |
Authors: | Younes Ben Taarit |
| |
Affiliation: | Institut de Recherches sur la Catalyse, CNRS, 69626 Villeurbanne Cedex, France |
| |
Abstract: | 13C NMR spectroscopy was used to investigate the nature of carbon monoxide adsorbed on transition metal ions hosted in a synthetic faujasite type zeolite. The adsorbed CO species was characterised by a highly shielded carbon nucleus. Using the Pople approximation for the paramagnetic shielding term, the observed chemical shift was rationalised assuming the formation of a cationic carbonyl species with an appreciable electronic transfer from the carbon lone pair to the transition metal ion and negligible π back-bonding if at all. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|