Slow motional NMR lineshapes for very anisotropic diffusion: I = 1 nuclei |
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| Authors: | Eva Meirovitch Jack H. Freed |
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| Affiliation: | Department of Chemistry, Cornell University, Ithaca, New York 14853, USA |
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| Abstract: | A general method to analyze NMR show motional lineshapes is extended to I = 1 nuclei and illustrated on 2H NMR lineshapes of a clathrate hydrate of tetrahydrofuran (THF-d8). It is shown that “ring puckering” could be the dominant mode of motion for the enclathrated THF-d8 molecule, whereas several other models are inconsistent with experiment. |
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