Viscosity dependence of the fluorescence lifetimes of cryptocyanine,pinacyanol and DDI

Viscosity dependence of the fluorescence lifetimes of cryptocyanine, pinacyanol and I, I'-diethyl-2,2'-dicarbocyanine iodide (DDI) has been studied by making relative quantum yield measurements in five solvents. It has also been established. by means of flash kinetic spectroscopy, that, in rigid solvents, φ^o_F+φ^o_IC ≈ 1 for all three dyes, where φ^o_F and φ^o_IC stand for the intrinsic quantum yields of fluorescence emission and internal conversion, respectively. Values of the intrisic rate constant of internal conversion are also presented.