The electronic spectrum of the triethylamine-perfluoro-tert-butanol complex |
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Authors: | P. Mercier P. Dupuis P. Sauvageau C. Sandorfy |
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Affiliation: | Département de Chimie, Université de Montréal, Montréal, Québec, Canada H3C 3V1 |
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Abstract: | The far-ultraviolet absorption spectrum of the triethylamine-perfluoro-tert-butanol complex has been measured in the gas phase. The photoelectron band of lowest energy has also been determined. It is about 13000 cm?1 higher than for free triethylamine. Up to at least 60000 cm?1, the UV spectrum is readily interpreted as a triethylamine spectrum shifted to higher frequencies by about 13000 cm?1. The bands of lowest frequency are the 3s and 3p Rydberg bands which follow the ionization potential. Up to 60000 cm?1, no charge transfer type band has been found. |
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