Detailed equilibrium principle in reversible bimolecular diffusion-controlled reactions |
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| Authors: | S.F. Burlatsky P.P. Levin I.V. Khudyakov V.A. Kuzmin A.A. Ovchinnikov |
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| Affiliation: | Institute of Chemical Physics, Academy of Sciences of the USSR, 117334 Moscow, USSR;Karpov Institute of Physical Chemistry, Obukha 10, Moscow, USSR |
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| Abstract: | The expressions for the observed rate constants of the forward bimolecular and back monomolecular reactions have been obtained using the boundary conditions imposed upon the reaction surfaces of each reagent particle. The rate, equilibrium and thermodynamical parameters of the back dissociation reactions of phenoxy radical dimers have been measured. The resultant values of kobs?1 as a function of solvent viscosity are accurately described by theoretical relationships obtained in the present work. |
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