Polarographic oxidation of some 5,10-dihydrophenazine derivatives |
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Authors: | I N Borukhova V F Gryazev I A Yarysheva Z V Pushkareva |
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Institution: | (1) S. M. Kirov Ural Polytechnic Institute, Sverdlovsk |
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Abstract: | The polarographic anode oxidation of 5-substituted dihydrophenazines in an aprotic medium and an aqueous acetone solution has one-electron or two-electron character. It was shown by means of the electronic and ESR spectra that the intermediates in the anode oxidation of dihydrophenazine and 5-methyldihydrophenazine are cation radicals and that the products of one-electron oxidation of 1,3-dinitro-5-aryl-substituted dihydrophenazines are phenazyl radicals. The final products of anode oxidation are phenazinium salts.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 548–551, April, 1976. |
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