Polar,non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts |
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| Authors: | Klingshirn Marc A Broker Grant A Holbrey John D Shaughnessy Kevin H Rogers Robin D |
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| Affiliation: | Department of Chemistry and Center for Green Manufacturing, University of Alabama, Box 870336, Tuscaloosa, AL 35487-0336, USA. |
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| Abstract: | The palladium-catalyzed copolymerization of styrene and CO in an ionic liquid solvent, 1-hexylpyridinium bis(trifluoromethanesulfonyl)imide, gave improved yields and increased molecular weights compared to polymerizations run in methanol. |
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