Structure-dependent transformations of the tetrachlorocyclopentadienone dimer and the product of its substitutive rearrangement in reactions with NaBH4, CrCl2, LiAlH4, and Zn |
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| Authors: | F A Gimalova O A Gavrilov M S Miftakhov |
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| Institution: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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| Abstract: | Dechlorination of the tetrachlorocyclopentadienone dimer and perchloro-7-oxotricyclo6.1.0.04,8]nona-2,5-diene-9-carboxylic acid N,N-diethylamide with hydride ion donors (NaBH4, LiAlH4, etc.) and electron donors (CrCl2 or Zn) were studied. The possible pathways of unusual transformations of both sterically hindered molecules are considered.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1001–1007, June, 2006. |
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| Keywords: | tetrachlorocyclopentadienone dimer cyclopropanes tricyclic compounds reduction dechlorination reductive dimerization aromatization organochlorine compounds |
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