| 基于1,3-二吗啉基丙烷的Hg(Ⅱ)和Zn(Ⅱ)配合物:合成、结构与抗菌活性 |
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| 作者姓名： | Goudarziafshar Hami Yousefi Somaieh Abbasityula Yunes Du&#;ek Michal Eigner V&#;clav Rezaeivala Maji &#;zbek Neslihan |
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| 作者单位： | Department of Chemistry, Faculty of Science, Sayyed Jamaleddinasadabadi University, Asadabad, Iran;Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516 Ilam, Iran;Department of Chemistry, Lorestan University, Khorramabad, Iran;Institute of Physics AS CR, v.v.i., Na Slovance 218221 Prague 8, Czech Republic;Institute of Physics AS CR, v.v.i., Na Slovance 218221 Prague 8, Czech Republic;Department of Chemical Engineering, Hamedan University of Technology, P.O. Box 65155 Hamedan, Iran;Department of Primary Education, Faculty of Education, Ahi Evran University, 40100 Krsehir, Turkey |
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| 基金项目： | Crystallography part was supported by the project (No.14-03276S) of the Czech Science Foundation. |
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| 摘 要： | 以1,3-二吗啉基丙烷(DMP)为配体合成了2个配合物：Hg(DMP)Cl2(1)和Zn(DMP)Cl2(2),并对其结构进行了表征。单晶X-射线结构分析表明,2个配合物中的金属离子都与2个N原子和2个Cl原子配位,形成扭曲四面体配位结构。配体和配合物对3种革兰氏阳性菌(S. aureus ATCC 25923,E. faecalis ATCC 23212和S. epidermidis ATCC 34384)和3种革兰氏阴性菌(E. coli ATCC 25922,P. aeruginosa ATCC 27853和K. pneumonia ATCC 70063)都具有抗菌活性,且在一定条件下,Hg(Ⅱ)配合物的抗菌活性超过了作为标准的磺胺异恶唑药物。
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| 关 键 词： | 晶体结构 1 3-吗啉基丙烷 抗菌活性 Hg(Ⅱ)配合物 Zn(Ⅱ)配合物 |
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