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Concentration relationships of coefficients of self-diffusion and viscosity of the adsorbate in narrow slit-like pores
Authors:Tovbin  Yu. K.  Vasyutkin  N. F.
Affiliation:(1) State Research Center of the Russian Federation "ldquo"L. Ya. Karpov Research Physicochemical Institute,"rdquo", 10 ul. Vorontsovo Pole, 103064 Moscow, Russian Federation
Abstract:Concentration relationships of dynamic characteristics of the adsorbate (coefficients of self-diffusion and shear viscosity) in narrow slit-like pores with different widths were considered. These coefficients were calculated using the simplest molecular model (lattice-gas model), which takes into account the intrinsic volume of molecules and their interactions in the quasi-chemical approximation. The values of coefficients of self-diffusion and shear viscosity of the adsorbate depend strongly on the distance to the pore wall.
Keywords:slit-like pores  adsorption  isotherm  coefficient of self-diffusion  coefficient of shear viscosity  lattice-gas model  quasichemical approximatio
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