Concentration relationships of coefficients of self-diffusion and viscosity of the adsorbate in narrow slit-like pores |
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Authors: | Tovbin Yu. K. Vasyutkin N. F. |
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Affiliation: | (1) State Research Center of the Russian Federation L. Ya. Karpov Research Physicochemical Institute,, 10 ul. Vorontsovo Pole, 103064 Moscow, Russian Federation |
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Abstract: | Concentration relationships of dynamic characteristics of the adsorbate (coefficients of self-diffusion and shear viscosity) in narrow slit-like pores with different widths were considered. These coefficients were calculated using the simplest molecular model (lattice-gas model), which takes into account the intrinsic volume of molecules and their interactions in the quasi-chemical approximation. The values of coefficients of self-diffusion and shear viscosity of the adsorbate depend strongly on the distance to the pore wall. |
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Keywords: | slit-like pores adsorption isotherm coefficient of self-diffusion coefficient of shear viscosity lattice-gas model quasichemical approximatio |
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