New bimetallic compounds based on the bis(thiosemicarbazonato) motif |
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Authors: | Christlieb Martin Cowley Andrew R Dilworth Jonathan R Donnelly Paul S Paterson Brett M Struthers Harriet S R White Jonathan M |
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Affiliation: | Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, UK. |
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Abstract: | Zinc and copper bis(thiosemicarbazonato) complexes containing more than one metal centre have been prepared with a view to examining their application for molecular imaging. The zinc complexes are fluorescent with excitation and emission at relatively long wavelengths. The dinuclear copper complex undergoes two sequential, quasi-reversible reductions. |
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