Proton magnetic relaxation and ionic conductivity of ammonium hydronium β″-alumina |
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Authors: | Yoshihiro Furukawa Yutaka Nakabayashi Shichio Kawai Osamu Nakamura |
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Affiliation: | The Institute of Scientific and Industrial Research, Osaka University, Ibaraki, Osaka 567, Japan;Government Industrial Research Institute, Osaka, Midorigaoka, Ikeda, Osaka 563, Japan |
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Abstract: | The protonic motion in NH+4-H+(H2O)nβ″ -alumina wasstudied by measurements of proton spin-lattice and spin-spin relaxation times. The results show that two types of NH+4 reorientation, that is, three-fold reorientation about its unique C3 axis and tumbling motion as a whole, occur below room temperature. Above room temperature a fast proton translational diffusion was apparent, and its activation energy was estimated to be 36 kJ/mol. On the other hand, the conductivity measured on a pressed sample by an ac method is strongly humidity-sensitiveand changes by more than five orders from 0 to 100% relative humidity. The activation energy also may be humidity-sensitive. Its value was 73 kJ/mol for the sample equilibrated at 90°C in a dry nitrogen atmosphere. |
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