Chemistry of 1,5-diketones: II. Specificity of transformations of polycyclic 1,5-diketones in acid media |
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Authors: | N V Pchelintseva Ya G Kolevatova L I Markova O V Fedotova P V Reshetov |
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Institution: | (1) Chernyshevskii Saratov State University, ul. Astrakhanskaya 83, Saratov, 410012, Russia |
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Abstract: | 2-(1,3-Diaryl-3-oxopropyl)cyclohexan-1-ones underwent carbo-and heterocyclization in a mixture of acetic acid with acetic anhydride in the presence of perchloric acid. The transformation of 2-(1,3-diaryl-3-oxopropyl)cyclohexan-1-ones into 2,4-diaryl-5,6,7,8-tetrahydrochromenylium salts was shown to involve intermediate 2,4-diarylbicyclo3.3.1]non-2-en-9-ones. The structure of 2,4-diaryl-substituted bicyclo3.3.1]non-2-en-9-ones and products of their reactions with halogens and hydroxylamine hydrochloride was confirmed by 1H and 13C NMR spectroscopy. |
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