| 手性(salen)Co配合物的合成及其在水解动力学拆分中的应用 |
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| 引用本文： | 蒋成君,陈志荣. 手性(salen)Co配合物的合成及其在水解动力学拆分中的应用[J]. 化学进展, 2008, 20(9): 1294-1305 |
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| 作者姓名： | 蒋成君 陈志荣 |
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| 作者单位： | 浙江大学化工系,杭州,310027;浙江科技学院生物与化学工程学院,杭州,310023;浙江大学化工系,杭州,310027 |
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| 摘 要： | 综述了近几年来手性(salen) Co金属配合物的合成及其在水解动力学拆分末端环氧化合物中的应用。设计更合适的配体、发展可重复利用的催化剂、对催化剂及催化体系进行理论和模拟是当前乃至今后该领域研究工作的重点。
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| 关 键 词： | 末端环氧化合物 水解动力学拆分 (salen)Co配合物 |
| 收稿时间： | 2007-10-10 |
| 修稿时间： | 2007-12-12 |
Synthesis of Chiral (salen) Co Complexes and Their Applications in Hydrolytic Kinetic Resolution |
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| Jiang Chengjun,Chen Zhirong. Synthesis of Chiral (salen) Co Complexes and Their Applications in Hydrolytic Kinetic Resolution[J]. Progress in Chemistry, 2008, 20(9): 1294-1305 |
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| Authors: | Jiang Chengjun Chen Zhirong |
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| Affiliation: | (1.Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, China; 2.Department of Biological and Chemical Engineering, Zhejiang University of Science and Technology, Hangzhou, 310023, China) |
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| Abstract: | Synthesis of the chiral (salen) Co complexes and their applications in racemic terminal epoxides are reviewed. The main aspects will be focused on designation of more suitable ligands, development of reusable highly enantioselective catalysts and simulation of the catalysts and catalytic systems. |
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| Keywords: | recemic terminal epoxides hydrolytix kinetic resolution(HKR) (salen)Co conplexes |
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