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Physicochemical properties and toxicological assessment of modified CdS nanoparticles
Authors:Andrea R da Silva  Ricardo Q Aucélio  Rosa I Rodríguez-Cotto  Mario G Ortiz-Martínez  Evasomary Rivera-Ramírez  Daniela Perroni Frias  Mariangela Macchione  Braulio Jiménez-Vélez  Adriana Gioda
Institution:1. Department of Analytical Chemistry, Faculty of Pharmacy, Gazi University, 06330, Ankara, Turkey
2. Department of Chemistry and Chemical Processing Technologies, K?r?kkale Vocational High School, K?r?kkale University, Yah?ihan, 71450, K?r?kkale, Turkey
3. Department of Food Engineering, Faculty of Engineering, Hacettepe University, Beytepe, 06800, Ankara, Turkey
5. Science Teaching Programme, Gazi Faculty of Education, Gazi University, 06500, Ankara, Turkey
6. Department of Biology, Faculty of Science, Gazi University, 06500, Ankara, Turkey
4. Department of Food Engineering, Faculty of Engineering and Food Research Center, Hacettepe University, Beytepe, 06800, Ankara, Turkey
7. Institut des Molécules et des Matériaux du Mans – IMMM – UMR CNRS 6283, Université du Maine, Av. O. Messiaen, 72085, Le Mans Cedex 9, France
Abstract:The synthesis procedure represents a key aspect in designing the physical and chemical properties of gold nanoparticles. The current study proposes a simple approach for gold nanoparticles synthesis using non-thermal plasma. The novelty of the setup consists in producing an in-liquid plasma discharge in argon bubbles that are externally generated in the solution exposed to treatment. Because plasma is the source of active species which are directly involved in gold reduction, no additional reducing agent was necessary. Collagen protein was used as capping agent. A plasma treatment of 10 min is sufficient for obtaining stable colloidal solutions with UV-Vis absorption maximum at 530 nm. Transmission electron microscopy images revealed preponderant spherical nanoparticles with dimensions in the range of 6–20 nm. The method of synthesis distinguishes by its good reproducibility, facility, efficiency, and ability to generate stable colloidal nanoparticles after several minutes of plasma exposure.
Keywords:
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