Synthesis and characterization of new N-phenylmaleimide thioglycosides |
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Authors: | Bader A. Salameh Kayed A. Abu-Safieh Sanaa R. A. Al-Kaabenah Raed A. Al-Qawasmeh |
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Affiliation: | 1. Department of Chemistry, The Hashemite University, P.O. Box 150459, Zarqa, 13115, Jordan 2. Department of Chemistry, The University of Jordan, Amman, 11942, Jordan
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Abstract: | Thioglycosides derivatives of N-phenylmaleimide have been prepared by the reaction of derivatives of 1-thio-d-glucopyranose, d-galactopyranose, d-lactose, and d-maltose with 3,4-dichloro-N-phenylmaleimide. The reaction of 3,4-dichloro-N-phenyl maleimide with sugar thiols (protected or unprotected) took place by displacement of both chlorine atoms by sulfide nucleophile giving the corresponding bis-thioglycoside products. |
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