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通过电沉积及氟硅烷改性而成的三维铜镍复合超疏水表面
引用本文:刘维仪,罗孟帆,罗 方,刘 燕,张延宗,沈 飞,张小洪,杨 刚,王莉淋,邓仕槐.通过电沉积及氟硅烷改性而成的三维铜镍复合超疏水表面[J].化学物理学报,2020,33(3):343-348.
作者姓名:刘维仪  罗孟帆  罗 方  刘 燕  张延宗  沈 飞  张小洪  杨 刚  王莉淋  邓仕槐
作者单位:四川农业大学环境学院,成都 611130
摘    要:将Cu-Ni微纳米颗粒电沉积在铝基底上,通过1H、1H、2H、2H-全氟癸基三甲氧基硅烷(FAS-17)对其进行修饰,制备了超双疏(SAP)表面. 采用扫描电子显微镜、X射线衍射、能量色散X射线光谱和傅里叶变换红外光谱对其形貌和化学成分进行了研究. 结果表明,SAP表面具有三维微纳结构,最大水接触角160.0°,油接触角151.6°. 进一步测试了SAP表面的机械强度和化学稳定性,结果显示该SAP表面具有优良的耐磨性、耐酸耐碱性能、自洁性和防污性能.

关 键 词:表面粗糙,微纳米结构,低表面能,自清洁,耐磨性,化学稳定性
收稿时间:2019/5/30 0:00:00

Three-Dimensional Cu-Ni Composite Superamphiphobic Surface via Electrodeposition and Fluorosilane Modi cation
Wei-yi Liu,Meng-fan Luo,Fang Luo,Yan Liu,Yan-zong Zhang,Fei Shen,Xiao-hong Zhang,Gang Yang,Li-lin Wang,Shi-huai Deng.Three-Dimensional Cu-Ni Composite Superamphiphobic Surface via Electrodeposition and Fluorosilane Modi cation[J].Chinese Journal of Chemical Physics,2020,33(3):343-348.
Authors:Wei-yi Liu  Meng-fan Luo  Fang Luo  Yan Liu  Yan-zong Zhang  Fei Shen  Xiao-hong Zhang  Gang Yang  Li-lin Wang  Shi-huai Deng
Institution:College of Environmental Sciences, Sichuan Agricultural University, Chengdu 611130, China
Abstract:A superamphiphobic (SAP) surface was fabricated by electrodepositing Cu-Ni micro-nano particles on aluminum substrate and modifying via 1H,1H,2H,2H-perfluorodecyltrimethoxysilane. Scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, and Fourier-transform infrared spectroscopy were employed to investigate the morphology and chemical composition. The results showed that the SAP surface had three-dimensional micro-nano structures and exhibited a maximum water contact angle of 160.0°, oil contact angle of 151.6°, a minimum water slide angle of 0°and oil slide angle of 9°. The mechanical strength and chemical stability of the SAP surface were tested further. The experimental results showed that the SAP surface presented excellent resistance to wear, prominent acid-resistance and alkali-resistance, self-cleaning and anti-fouling properties.
Keywords:Rough surface  Micro-nano structure  Low surface energy  Self-cleaning  Wear resistance  Chemical stability
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