13C-13C Spin-Spin Coupling Constants in Structural Studies: XXXI. Bicyclo[2.1.0]pentane Heteroanalogs |
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| Authors: | Kuznetsova T A Istomina N V Krivdin L B |
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| Institution: | (1) Angarsk State Institute of Technology, ul. Chaikovskogo 60, Angarsk, 665835, Russia |
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| Abstract: | 13C-13C spin-spin coupling constants and orbital hybridization of the bridging bond in bicyclo2.1.0]pentane heteroanalogs and their unsaturated derivatives were calculated in terms of the self-consistent finite perturbation theory (SCPT INDO). The results showed that the bridging CÄC bond in all the examined compounds has an anomaloulsy low s character. |
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