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Determination of Sulfate Groups in Complex Mixtures by Infrared Spectroscopy
Authors:O. A. Zalkind  D. V. Makarov  V. N. Makarov
Affiliation:(1) Tananaev Institute of Chemistry and Technology of Rare-Earth Elements and Mineral Raw Materials of the Kola Scientific Center, Russian Academy of Sciences, ul. Fersmana 26a, Apatity, 184209, Russia
Abstract:The possibility of the quantitative determination of sulfates in mixtures containing copper and nickel carbonates and sulfides was investigated. It was found that, for 0.1–50 wt % of sulfate (gypsum), the ratio of intensities of the absorption bands in the IR spectrum of the mixture in the range 700–600 cm–1 is a linear function of its concentration. This dependence can be used for the determination of trace sulfates.
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