Calculation of the Magnetic Properties of Low-Symmetry Polynuclear Complexes. Exchange Interactions in the Hexanuclear Chromium(III) Pivalate |
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| Authors: | Yu V Rakitin A A Smith |
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| Institution: | (1) Institute of Rare Element and Mineral Chemistry and Technology, Kola Research Center, Russian Academy of Sciences, ul. Fersmana 14, Apatity, Murmansk oblast, 184200, Russia;(2) University of Manchester, UK |
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| Abstract: | A theory that allows numerical calculations and interpretation of magnetic properties of low-symmetry polynuclear complexes containing a large number of orbitally non-degenerate transition metal ions is developed by the irreducible tensor operator method. The potential of the theory was illustrated using the chromium(III) complex, Cr6O2(OH)2O2CC(CH3)3]11 as an example.__________Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 7, 2005, pp. 518–522.Original Russian Text Copyright © 2005 by Rakitin, Smith. |
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