Interpretation of energy stability for Ti27+ and Ti26+ dimers |
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Authors: | N N Bulgakov V F Anufrienko and V V Zakharov |
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Institution: | (1) Institute of Catalysis, 630090 Novosibirsk, USSR |
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Abstract: | By using the interacting bonds method (IBM), it has been established that for the chloride Ziegler systems (TiCl4+AlR3) for polymerization the formation of Ti
2
7+
and Ti
2
6+
pairs is a thermodynamically favorable process.
![Dcy](/content/m840qh6646120p64/xxlarge1044.gif) ![lcy](/content/m840qh6646120p64/xxlarge1083.gif) ![khcy](/content/m840qh6646120p64/xxlarge1093.gif) ![lcy](/content/m840qh6646120p64/xxlarge1083.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![rcy](/content/m840qh6646120p64/xxlarge1088.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![dcy](/content/m840qh6646120p64/xxlarge1076.gif) ![ncy](/content/m840qh6646120p64/xxlarge1085.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![tscy](/content/m840qh6646120p64/xxlarge1094.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![gcy](/content/m840qh6646120p64/xxlarge1075.gif) ![lcy](/content/m840qh6646120p64/xxlarge1083.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) ![rcy](/content/m840qh6646120p64/xxlarge1088.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![vcy](/content/m840qh6646120p64/xxlarge1074.gif) ![scy](/content/m840qh6646120p64/xxlarge1089.gif) ![kcy](/content/m840qh6646120p64/xxlarge1082.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![scy](/content/m840qh6646120p64/xxlarge1089.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![scy](/content/m840qh6646120p64/xxlarge1089.gif) ![tcy](/content/m840qh6646120p64/xxlarge1090.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) ![mcy](/content/m840qh6646120p64/xxlarge1084.gif) ![pcy](/content/m840qh6646120p64/xxlarge1087.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![lcy](/content/m840qh6646120p64/xxlarge1083.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![mcy](/content/m840qh6646120p64/xxlarge1084.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) ![rcy](/content/m840qh6646120p64/xxlarge1088.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![zcy](/content/m840qh6646120p64/xxlarge1079.gif) ![acy](/content/m840qh6646120p64/xxlarge1072.gif) ![tscy](/content/m840qh6646120p64/xxlarge1094.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) (TiCl4+AlR3) ![mcy](/content/m840qh6646120p64/xxlarge1084.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) ![tcy](/content/m840qh6646120p64/xxlarge1090.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![dcy](/content/m840qh6646120p64/xxlarge1076.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![vcy](/content/m840qh6646120p64/xxlarge1074.gif) ![zcy](/content/m840qh6646120p64/xxlarge1079.gif) ![acy](/content/m840qh6646120p64/xxlarge1072.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![mcy](/content/m840qh6646120p64/xxlarge1084.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![dcy](/content/m840qh6646120p64/xxlarge1076.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) ![jcy](/content/m840qh6646120p64/xxlarge1081.gif) ![scy](/content/m840qh6646120p64/xxlarge1089.gif) ![tcy](/content/m840qh6646120p64/xxlarge1090.gif) ![vcy](/content/m840qh6646120p64/xxlarge1074.gif) ![ucy](/content/m840qh6646120p64/xxlarge1091.gif) ![yucy](/content/m840qh6646120p64/xxlarge1102.gif) ![shchcy](/content/m840qh6646120p64/xxlarge1097.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![scy](/content/m840qh6646120p64/xxlarge1089.gif) ![vcy](/content/m840qh6646120p64/xxlarge1074.gif) ![yacy](/content/m840qh6646120p64/xxlarge1103.gif) ![zcy](/content/m840qh6646120p64/xxlarge1079.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) (![Mcy](/content/m840qh6646120p64/xxlarge1052.gif) ![Vcy](/content/m840qh6646120p64/xxlarge1042.gif) ) ![pcy](/content/m840qh6646120p64/xxlarge1087.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![kcy](/content/m840qh6646120p64/xxlarge1082.gif) ![acy](/content/m840qh6646120p64/xxlarge1072.gif) ![zcy](/content/m840qh6646120p64/xxlarge1079.gif) ![acy](/content/m840qh6646120p64/xxlarge1072.gif) ![ncy](/content/m840qh6646120p64/xxlarge1085.gif) , ![chcy](/content/m840qh6646120p64/xxlarge1095.gif) ![tcy](/content/m840qh6646120p64/xxlarge1090.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![bcy](/content/m840qh6646120p64/xxlarge1073.gif) ![rcy](/content/m840qh6646120p64/xxlarge1088.gif) ![acy](/content/m840qh6646120p64/xxlarge1072.gif) ![zcy](/content/m840qh6646120p64/xxlarge1079.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![vcy](/content/m840qh6646120p64/xxlarge1074.gif) ![acy](/content/m840qh6646120p64/xxlarge1072.gif) ![ncy](/content/m840qh6646120p64/xxlarge1085.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![pcy](/content/m840qh6646120p64/xxlarge1087.gif) ![acy](/content/m840qh6646120p64/xxlarge1072.gif) Ti
2
7+
Ti
2
6+
![yacy](/content/m840qh6646120p64/xxlarge1103.gif) ![vcy](/content/m840qh6646120p64/xxlarge1074.gif) ![lcy](/content/m840qh6646120p64/xxlarge1083.gif) ![yacy](/content/m840qh6646120p64/xxlarge1103.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) ![tcy](/content/m840qh6646120p64/xxlarge1090.gif) ![scy](/content/m840qh6646120p64/xxlarge1089.gif) ![zcy](/content/m840qh6646120p64/xxlarge1079.gif) ![acy](/content/m840qh6646120p64/xxlarge1072.gif) ![mcy](/content/m840qh6646120p64/xxlarge1084.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) ![tcy](/content/m840qh6646120p64/xxlarge1090.gif) ![ncy](/content/m840qh6646120p64/xxlarge1085.gif) ![tcy](/content/m840qh6646120p64/xxlarge1090.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) ![rcy](/content/m840qh6646120p64/xxlarge1088.gif) ![mcy](/content/m840qh6646120p64/xxlarge1084.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![dcy](/content/m840qh6646120p64/xxlarge1076.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![ncy](/content/m840qh6646120p64/xxlarge1085.gif) ![acy](/content/m840qh6646120p64/xxlarge1072.gif) ![mcy](/content/m840qh6646120p64/xxlarge1084.gif) ![icy](/content/m840qh6646120p64/xxlarge1080.gif) ![chcy](/content/m840qh6646120p64/xxlarge1095.gif) ![iecy](/content/m840qh6646120p64/xxlarge1077.gif) ![scy](/content/m840qh6646120p64/xxlarge1089.gif) ![kcy](/content/m840qh6646120p64/xxlarge1082.gif) ![vcy](/content/m840qh6646120p64/xxlarge1074.gif) ![ycy](/content/m840qh6646120p64/xxlarge1099.gif) ![gcy](/content/m840qh6646120p64/xxlarge1075.gif) ![ocy](/content/m840qh6646120p64/xxlarge1086.gif) ![dcy](/content/m840qh6646120p64/xxlarge1076.gif) ![ncy](/content/m840qh6646120p64/xxlarge1085.gif) ![ycy](/content/m840qh6646120p64/xxlarge1099.gif) .
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