Synthesis and magnetic properties of a highly conducting neutral nickel complex with a highly conjugated tetrathiafulvalenedithiolate ligand |
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| Authors: | Wen He-Rui Li Cheng-Hui Song You Zuo Jing-Lin Zhang Bin You Xiao-Zeng |
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| Affiliation: | Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China. |
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| Abstract: | A neutral nickel complex with the extended tetrathiafulvalene-4,5-dithiolate ligand benzotetrathiafulvalenedithiolate (btdt2-) is synthesized and characterized. From the structural analysis, the neighboring molecules in this complex are stacked in a different way compared to the previously reported single-component metal [Ni(tmdt)2]. The computational studies confirm that the difference in molecular packing results in the variance of conductivity. |
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