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回火处理对LiNi1/3Co1/3Mn1/3O2结构和电化学性能的影响
引用本文:闫芳,叶乃清,田华,钟卓洪.回火处理对LiNi1/3Co1/3Mn1/3O2结构和电化学性能的影响[J].化学通报,2011,74(5):429-433.
作者姓名:闫芳  叶乃清  田华  钟卓洪
作者单位:有色金属及材料加工新技术教育部重点实验室,桂林理工大学材料科学与工程学院,桂林,541004
摘    要:以硝酸锂、四水合乙酸镍、四水合乙酸钴、四水合乙酸锰、氨水和草酸为原料,通过共沉淀-燃烧法合成了锂离子电池正极材料LiNi1/3Co1/3Mn1/3O2,采用XRD、SEM和充放电试验对合成产物进行了表征,研究了回火处理对合成产物结构和电化学性能的影响.实验结果表明,嫩烧反应形成的LiNi1/3C1/3Mn31/3O2结...

关 键 词:锂离子电池  正极材料  LiNi1/3Co1/3Mn1/3O2  共沉淀-燃烧法

Effects of Reheat Process on the Structure and Electrochemical Performance of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2
Yan Fang,Ye Naiqing,Tian Hua,Zhong Zhuohong.Effects of Reheat Process on the Structure and Electrochemical Performance of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2[J].Chemistry,2011,74(5):429-433.
Authors:Yan Fang  Ye Naiqing  Tian Hua  Zhong Zhuohong
Institution:Yan Fang,Ye Naiqing,Tian Hua,Zhong Zhuohong(Key Laboratory of New Processing Technology for Nonferrous Metals and Materials,Ministry ofEducation,College of Material Science and Engineering,Guilin University of Technology,Guilin 541004)
Abstract:The cathode material LiNi1/3 Co1/3 Mn1/3 O2 for lithium-ion batteries was synthesized in air bycoprecipitation-combustion process using LiNO3,Ni(CH3 COO)2.4H2 O,Co(CH3 COO)2.4H2 O,Mn(CH3 COO)2.4H2 O,NH3.H2 O and H2 C2 O4.2H2 O as starting materials.The products were characterized by powder X-raydiffraction,SEM and charge-discharge test.The effects of reheat process on the structure and electrochemicalperformances of the synthesized products were investigated.The results indicated that the LiNi1/3 Co1/3 Mn1/...
Keywords:LiNi1/3Co1/3Mn1/3O2
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