首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Sustainable radical reduction through catalytic hydrogen atom transfer
Authors:Gansäuer Andreas  Fan Chun-An  Piestert Frederik
Institution:Kekulé-Institut für Organische Chemie and Biochemie der Universit?t Bonn, Gerhard Domagk Strasse 1, 53121 Bonn, Germany. andreas.gansaeuer@uni-bonn.de
Abstract:A system with coupled catalytic cycles is described that allows radical reduction by hydrogen atom abstraction from rhodium hydrides. These intermediates are generated from H2 activation by Wilkinson's catalyst. Radical generation is carried out by titanocene-catalyzed electron transfer to epoxides.
Keywords:
本文献已被 PubMed 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号