Sustainable radical reduction through catalytic hydrogen atom transfer |
| |
| Authors: | Gansäuer Andreas Fan Chun-An Piestert Frederik |
| |
| Institution: | Kekulé-Institut für Organische Chemie and Biochemie der Universit?t Bonn, Gerhard Domagk Strasse 1, 53121 Bonn, Germany. andreas.gansaeuer@uni-bonn.de |
| |
| Abstract: | A system with coupled catalytic cycles is described that allows radical reduction by hydrogen atom abstraction from rhodium hydrides. These intermediates are generated from H2 activation by Wilkinson's catalyst. Radical generation is carried out by titanocene-catalyzed electron transfer to epoxides. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
