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RCTA Techniques Used in Studies of Solid State Reactions in Inorganic Compounds
Authors:Sørensen  O T
Institution:1.Ris? National Laboratory, DK-4000, Roskilde, Denmark
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Abstract:The Reaction Controlled Thermal Analysis techniques, RCTA, are very useful both in thermogravimetric and dilatometric studies. In the present paper this big family of techniques is divided into three main classes: Quasi-Isothermal techniques (QIA); Controlled Reaction Rate Thermal Analysis (CRTA) and Reaction (Event) Controlled Heating Rate Adaption. After a short presentation of these techniques and the general advantages of RCTA, two examples of kinetic studies on thermal decomposition of Ba- and Ce oxalates by using Stepwise Isothermal Analysis, SIA, introduced by the author is presented and discussed. This revised version was published online in July 2006 with corrections to the Cover Date.
Keywords:kinetics  reaction controlled thermal analysis  stepwise isothermal analysis  thermogravimetry
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