Synthesis of Sulfides by Reactions of 1,1-Dichloro-2-chloro-methylcyclopropane with S-Nucleophiles |
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Authors: | E I Mikhed’kina P V Nedel’ko V V Prezhdo |
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Institution: | (1) “Khar’kovskii politekhnicheskii institut” National Technical University, ul. Frunze 21, Khar’kov, 61002, Ukraine;(2) Institute of Chemistry, J. Kochanowski Higher Pedagogical School, Kielce, Poland |
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Abstract: | 1,1-Dichloro-2-chloromethylcyclopropane reacts with thiolates to give 2,2-dichlorocyclopropylmethyl sulfides via replacement of the side-chain chlorine atom. The resulting sulfides are readily oxidized to the corresponding sulfones.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 3, 2005, pp. 381–386.Original Russian Text Copyright © 2005 by Mikhed’kina, Nedel’ko, Prezhdo. |
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