Eosin Y catalyzed visible light oxidative C-C and C-P bond formation |
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Authors: | Hari Durga Prasad König Burkhard |
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Institution: | Institut fu?r Organische Chemie, Universita?t Regensburg, Universita?tsstrasse 31, D-93053 Regensburg, Germany. |
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Abstract: | Eosin Y catalyzes efficiently the visible light mediated coupling of sp(3) C-H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the absence of an external oxidant. Nitroalkanes, dialkyl malonates, malononitrile, and dialkyl phophonates were used as pronucleophiles in this metal-free, visible light oxidative coupling reaction. |
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