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Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate
引用本文:Yun Xing YAN, Qi FANG, Wen Tao YU, Yu Peng TIAN, Duo Rong YUAN,Xin Qiang WANG, Fan Qing MENG, (Institute of Crystal Materials and State Key Laboratory of Crystal Materials,Shandong University,Jinan,250100)Zhi Gang CAI, Ling Zhi ZHANG (Institute of Laser. Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate[J]. 中国化学快报, 1998, 0(12)
作者姓名:Yun Xing YAN   Qi FANG   Wen Tao YU   Yu Peng TIAN   Duo Rong YUAN  Xin Qiang WANG   Fan Qing MENG   (Institute of Crystal Materials and State Key Laboratory of Crystal Materials  Shandong University  Jinan  250100)Zhi Gang CAI   Ling Zhi ZHANG (Institute of Laser
作者单位:Yun Xing YAN; Qi FANG; Wen Tao YU; Yu Peng TIAN; Duo Rong YUAN;Xin Qiang WANG; Fan Qing MENG; (Institute of Crystal Materials and State Key Laboratory of Crystal Materials,Shandong University,Jinan,250100
摘    要:IntroductionTheMHg(SCN)4seriesofcrystallinecomplexeshavebeenknowninanalyticalchemistryfortheircharacteristicshapesand..l.,,i.Withthedevelopmentofnon-linearoptics(NLO),thiskindofcoordinationcompoundshavebeendiscoveredtobeusefulasNLOmaterials.In1970s,ItwasreportedthattheN'LOcoefficient(fordoublinginfraredI.064urnNd:YAGlaserbeamtogenerate0.532urngreenlight)ofCdHg(SCN)4wasI.3timesasthatofNLOcrystalLiIO,'.Furthermore,wehaverecentlydiscoveredthattheCdHg(SCN)'crystalcangeneratesecondha…


Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate
Yun Xing YAN, Qi FANG, Wen Tao YU, Yu Peng TIAN, Duo Rong YUAN,Xin Qiang WANG, Fan Qing MENG,. Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate[J]. Chinese Chemical Letters, 1998, 0(12)
Authors:Yun Xing YAN   Qi FANG   Wen Tao YU   Yu Peng TIAN   Duo Rong YUAN  Xin Qiang WANG   Fan Qing MENG  
Abstract:Iron Mercury Tetrathiocyanate (FeHg(SCN)4) has been synthesized and its structure hasbeen detendned. It belongs to the tetragonal system, 14 space group. The Hg-S-C=N-Fe bridgeleeds to the formation of an infinite three dimensional network. Irrsdiated by a 1.064 nm Nd:YAG laser beam, FeHg(SCN)4 showed a 0.532 nm second harmonic intensity which is 0.6 times asthat of organic nonlinear optical crystal urea.
Keywords:FeHg(SCN)_4  synthesis  structure  nonlinear property
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