| Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate |
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| 作者姓名： | Yun Xing YAN Qi FANG Wen Tao YU Yu Peng TIAN Duo Rong YUAN Xin Qiang WANG Fan Qing MENG |
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| 作者单位： | Yun Xing YAN; Qi FANG; Wen Tao YU; Yu Peng TIAN; Duo Rong YUAN;Xin Qiang WANG; Fan Qing MENG; (Institute of Crystal Materials and State Key Laboratory of Crystal Materials，Shandong University，Jinan，250100 |
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| 摘 要： | IntroductionTheMHg(SCN)4seriesofcrystallinecomplexeshavebeenknowninanalyticalchemistryfortheircharacteristicshapesand..l.,,i.Withthedevelopmentofnon-linearoptics(NLO),thiskindofcoordinationcompoundshavebeendiscoveredtobeusefulasNLOmaterials.In1970s,ItwasreportedthattheN'LOcoefficient(fordoublinginfraredI.064urnNd:YAGlaserbeamtogenerate0.532urngreenlight)ofCdHg(SCN)4wasI.3timesasthatofNLOcrystalLiIO,'.Furthermore,wehaverecentlydiscoveredthattheCdHg(SCN)'crystalcangeneratesecondha…
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Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate |
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| Yun Xing YAN, Qi FANG, Wen Tao YU, Yu Peng TIAN, Duo Rong YUAN,Xin Qiang WANG, Fan Qing MENG,.Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate[J].Chinese Chemical Letters,1998(12). |
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| Authors: | Yun Xing YAN Qi FANG Wen Tao YU Yu Peng TIAN Duo Rong YUAN Xin Qiang WANG Fan Qing MENG |
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| Abstract: | Iron Mercury Tetrathiocyanate (FeHg(SCN)4) has been synthesized and its structure hasbeen detendned. It belongs to the tetragonal system, 14 space group. The Hg-S-C=N-Fe bridgeleeds to the formation of an infinite three dimensional network. Irrsdiated by a 1.064 nm Nd:YAG laser beam, FeHg(SCN)4 showed a 0.532 nm second harmonic intensity which is 0.6 times asthat of organic nonlinear optical crystal urea. |
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| Keywords: | FeHg(SCN)_4 synthesis structure nonlinear property |
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