ESR studies of α-hydro p-substituted phenyl nitroxides and correlation analysis of their HFSC values |
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Authors: | Hong-Yan Xu Zhang-Ke Yu Zhao Chen-Lin Cheng-Xue Zhao |
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Institution: | (1) Chemistry Department, Shanghai Jiao-Tong University, 200240 Shanghai, China;(2) Shanghai Institute of Organic Chemistry, 200032 Shanghai, China |
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Abstract: | Well-resolved ESR spectra of a series of α-hydro p-substituted phenyl nitroxides were obtained in the fast ET reactions of p-substituted anilines with perfluoroacyl peroxides in F113 (CCl2FCClF2) solutions and one parameter (σ or σ·) as well as dual-parameter (σ, σ·) correlation analyses of their hyperfine splitting constants were conducted. |
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