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ESR studies of α-hydro p-substituted phenyl nitroxides and correlation analysis of their HFSC values
Authors:Hong-Yan Xu  Zhang-Ke  Yu Zhao  Chen-Lin  Cheng-Xue Zhao
Institution:(1) Chemistry Department, Shanghai Jiao-Tong University, 200240 Shanghai, China;(2) Shanghai Institute of Organic Chemistry, 200032 Shanghai, China
Abstract:Well-resolved ESR spectra of a series of α-hydro p-substituted phenyl nitroxides were obtained in the fast ET reactions of p-substituted anilines with perfluoroacyl peroxides in F113 (CCl2FCClF2) solutions and one parameter (σ or σ·) as well as dual-parameter (σ, σ·) correlation analyses of their hyperfine splitting constants were conducted.
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