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Mossbauer study of reactions of Sn[Fe(CN)_6] on supports
引用本文:HUA,Wan-Sen CHEN,Shou-Wen YANG,Xu-Jie LU,Lu-De WANG,XinMaterials Chemistry Laboratory,Nanjing University of Science and Technology,Nanjing,Jiangsu 210094,China. Mossbauer study of reactions of Sn[Fe(CN)_6] on supports[J]. 中国化学, 1997, 0(1)
作者姓名:HUA  Wan-Sen CHEN  Shou-Wen YANG  Xu-Jie LU  Lu-De WANG  XinMaterials Chemistry Laboratory  Nanjing University of Science and Technology  Nanjing  Jiangsu 210094  China
作者单位:HUA,Wan-Sen CHEN,Shou-Wen YANG,Xu-Jie LU,Lu-De WANG,XinMaterials Chemistry Laboratory,Nanjing University of Science and Technology,Nanjing,Jiangsu 210094,China
基金项目:Project supported by the Natural Science Foundation of Jiangsu,China.
摘    要:Mossbauer spectroscopy has been applied to the investigation of reaction of Sn[Fe(CN)6] on magnesia, 7-alumina, silica and activated carbon. It was found that the thermal decomposition products of supported Sn[Fe(CN)6] are quite different from those of the unsupported one as a result of the interaction between the complex and supports. The supports could promote the oxidation in the air atmosphere and their effect led to high dispersion of the decomposition products on the surface.


Mossbauer study of reactions of Sn[Fe(CN)6] on supports
HUA,Wan-Sen CHEN,Shou-Wen YANG,Xu-Jie LU,Lu-De WANG,XinMaterials Chemistry Laboratory,Nanjing University of Science and Technology,Nanjing,Jiangsu ,China. Mossbauer study of reactions of Sn[Fe(CN)6] on supports[J]. Chinese Journal of Chemistry, 1997, 0(1)
Authors:HUA  Wan-Sen CHEN  Shou-Wen YANG  Xu-Jie LU  Lu-De WANG  XinMaterials Chemistry Laboratory  Nanjing University of Science  Technology  Nanjing  Jiangsu   China
Affiliation:HUA,Wan-Sen CHEN,Shou-Wen YANG,Xu-Jie LU,Lu-De WANG,XinMaterials Chemistry Laboratory,Nanjing University of Science and Technology,Nanjing,Jiangsu 210094,China
Abstract:Mossbauer spectroscopy has been applied to the investigation of reaction of Sn[Fe(CN)6] on magnesia, 7-alumina, silica and activated carbon. It was found that the thermal decomposition products of supported Sn[Fe(CN)6] are quite different from those of the unsupported one as a result of the interaction between the complex and supports. The supports could promote the oxidation in the air atmosphere and their effect led to high dispersion of the decomposition products on the surface.
Keywords:Sn[Fe(CN)6]   support   decomposition   Mossbauer spectra
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