| C60与有机胺电荷转移配合物的吸光特性比较研究 |
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| 引用本文： | 乔锦丽 晋卫军. C60与有机胺电荷转移配合物的吸光特性比较研究[J]. 光谱学与光谱分析, 1999, 19(6): 794-797 |
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| 作者姓名： | 乔锦丽 晋卫军 |
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| 作者单位： | 山西大学化学系 |
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| 摘 要： | 考察了甲苯、ＣＣｌ４和环己烷三种溶剂体系中，Ｃ６０同Ｎ，Ｎ二甲基苯胺（ＤＮＡ）、二乙胺（ＤＥＡ）及三乙胺（ＴＥＡ）电荷转移配合物（ＣＴＣ）的吸光特性。发现不同胺同Ｃ６０作用的程度在不同溶剂介质中均存在如下顺序：环己烷〉ＣＣｌ４〉甲苯。而在同一溶剂介质中，不同胺同Ｃ６０作用的程度各不相同。测定了电转移配合物在不同溶剂介质中的摩尔吸光系数及形成常数，并考察了温度对电荷转移配合物形成常数的影响。
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| 关 键 词： | 电荷转移配合物 二甲基苯胺 二乙胺 三乙胺 碳60 |
Comparative Studies on the Absorption Properties of Charge Transfer Complexes of C _(60) with Three Organic Amines |
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| J Qiao,W Jin. Comparative Studies on the Absorption Properties of Charge Transfer Complexes of C _(60) with Three Organic Amines[J]. Spectroscopy and Spectral Analysis, 1999, 19(6): 794-797 |
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| Authors: | J Qiao W Jin |
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| Affiliation: | Department of Chemistry, Shanxi University, 030006 Taiyuan. |
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| Abstract: | Comparative studies on the absorption properties of charge transfer complexes of C 60 with N,N dimethylaniline,diethylamine and triethylamine in toluene,CCl 4 and cyclohexane were carried out,respectively.It was found that interactions of C 60 with various amines in different solvent media are all in the order:cyclohexane>CCl 4>toluene,while these interactions are different in the same solvent.Both of the molar extinction coefficients and apparent constants of CTC were determined.Meanwhile,the influences of temperature on CT interactions of C 60 with various amines in different solvent media were also studied. |
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| Keywords: | C 60 Charge transfer complexes Absorbance N N dimethylaniline Diethylamine Triethylamine |
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