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Bi系高温氧化物超导体CuO2面内Cu-O键伸缩振动的分析
引用本文:胥荣,汤宏,李村涓,鲜于泽. Bi系高温氧化物超导体CuO2面内Cu-O键伸缩振动的分析[J]. 光谱学与光谱分析, 1999, 19(1): 44-46
作者姓名:胥荣  汤宏  李村涓  鲜于泽
作者单位:1. 辽宁大学物理系,110036,沈阳
2. 中国科学院金属所,110015,沈阳
3. 东北大学物理系,110006,沈阳
摘    要:测试了一系列Bi系高温氧化物超导体的红外吸收谱,分析了Bi系超导样品CuO2面内Cu-O键的伸缩振动与样品超电性的联系。结果表明,CuO2面内Cu-O伸缩振动吸收峰强度的变化与样品零电阻的变化一致,其原因与微观结构内部声子与载流子的相互作用密切相关。其次,根据分子振动理论,采用简化模型计算了Bi系超导体CuO2面内Cu-O振支频率

关 键 词:Bi系超导体  红外吸收谱  Cu-O键伸缩振动

Analysis of Cu-O Bond Stretching Vibration in CuO2 Plane of Bi-System High Temperature Superconductor
Rong XU,Hong TANG,Cunjuan LI,Yuze XIAN. Analysis of Cu-O Bond Stretching Vibration in CuO2 Plane of Bi-System High Temperature Superconductor[J]. Spectroscopy and Spectral Analysis, 1999, 19(1): 44-46
Authors:Rong XU  Hong TANG  Cunjuan LI  Yuze XIAN
Affiliation:Department of Physics, Liaoning University, 110036 Shenyang.
Abstract:Infrared absorption spectra of Bi system high zero resistance temperature( T c ) superconductors were measured.The relation between Cu O bond stretching vibration in CuO 2 plane and superconducting properties of Bi system high T c superconductors were analysed and discussed.The result of analysis indicated that the change of absorption peak strength of Cu O bond stretching vibration was similar to the change of T c .The reason was related to the coupling between the phonon and free carrier.And according to the theory of molecule vibration,the frequencies of Cu O bond stretching vibration in CuO 2 plane were calculated on the base of simplified model.
Keywords:Bi system superconductor   Infrared absorption spectrum   Cu O bond stretching vibration
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