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CuⅠ-AsⅤ离子3d104s-3d94s4p跃迁组态的能级和振子强度
引用本文:牟致栋,张学龙.CuⅠ-AsⅤ离子3d104s-3d94s4p跃迁组态的能级和振子强度[J].光谱学与光谱分析,1999,19(4):518-520.
作者姓名:牟致栋  张学龙
作者单位:中国矿业大学数力系,221008,徐州
基金项目:中国矿业大学校科研和教改项目 
摘    要:利用组态相互作用理论和参数拟合内插的方法计算了类铜CuⅠ-AsⅤ离子3d104s-3d94s4p跃迁组态的能级、谱线波长和电偶极跃迁的振子强度。3d94s4p组态能级的所有计算结果与现有实验数据符合得很好。而ZnⅡ和GaⅢ离子的大部分能级纯属预测计算结果。给出了3d104s-3d94s4p能级跃迁的谱线波长和振子强度。

关 键 词:组态相互作用理论  跃迁组态的能级  振子强度

The Energy Levels and Oscillator Strengths for Transitions 3d104s-3d94s4p in Ions from CuⅠ-AsⅤ
Zhidong MU,Xuelong ZHANG.The Energy Levels and Oscillator Strengths for Transitions 3d104s-3d94s4p in Ions from CuⅠ-AsⅤ[J].Spectroscopy and Spectral Analysis,1999,19(4):518-520.
Authors:Zhidong MU  Xuelong ZHANG
Institution:Department of Mathematics & Mechanics, China University of Mining & Technology, 221008 Xuzhou.
Abstract:The energy levels of configurations 3d(10)4s and 3d(9)4s4p of copper-like ions from Cu I to As V were calculated by means of the configuration interaction theory and parametric fit interpolation method. Calculated energy levels of 3d(9)4s4p are all in good agreement with experimental values . Most energy levels of ions Zn II and Ga III are sheer predicated ones. Also, the transition wavelengths and corresponding oscillator strengths of 3d(10)4s-3d(9)4s4p were calculated.
Keywords:Configuration interaction theory    Atomic energy levels    Oscillator strengths
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